Water-splitting Mn4CaO5 cluster
Umena and colleagues solved the structure of photosystem II at 1.9 Å, locating every metal atom of the Mn4CaO5 cluster where water is split, with five oxygen bridges and four bound water molecules.
As reported in: Umena, Kawakami, Shen et al. (2011). Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å. Nature. doi:10.1038/nature09913