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Chapin, Fuller and Pearson at Bell Labs reported a silicon p-n junction photocell for turning sunlight into electrical power.
As reported in: Chapin, Fuller, Pearson (1954). A New Silicon <i>p-n</i> Junction Photocell for Converting Solar Radiation into Electrical Power. Journal of Applied Physics. doi:10.1063/1.1721711
Tang made a two-layer organic cell from copper phthalocyanine and a perylene derivative with about 1% efficiency, showing the organic–organic interface is key.
Yu and colleagues blended a polymer with C60 fullerenes, raising efficiency to about 2.9%, over two orders of magnitude better than the pure polymer.
As reported in: Yu, Gao, Hummelen et al. (1995). Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions. Science. doi:10.1126/science.270.5243.1789
Shockley and Queisser calculated the detailed-balance limit for p-n junction solar cells, a maximum of about 30% for a 1.1 eV band gap.
As reported in: Shockley, Queisser (1961). Detailed Balance Limit of Efficiency of
<i>p-n</i>
Junction Solar Cells. Journal of Applied Physics. doi:10.1063/1.1736034